{"id":3719,"date":"2021-11-23T06:34:29","date_gmt":"2021-11-23T06:34:29","guid":{"rendered":"https:\/\/www.ahotech.com\/?p=3719"},"modified":"2021-11-24T12:15:41","modified_gmt":"2021-11-24T12:15:41","slug":"spanningshysteresfenomenet-hos-litiumtionylkloridbatterier-och-dess-elimineringsmetod","status":"publish","type":"post","link":"https:\/\/www.ahotech.com\/sv\/2021\/11\/voltage-hysteresis-phenomenon-of-lithium-thionyl-chloride-battery-and-its-elimination-method\/","title":{"rendered":"Sp\u00e4nningshysteresfenomenet hos litiumtionylkloridbatterier och dess elimineringsmetod"},"content":{"rendered":"

Fenomenet sp\u00e4nningshysteres uppst\u00e5r n\u00e4r litiumsubbatterier urladdas med h\u00f6g str\u00f6m efter l\u00e5ngvarig lagring med l\u00e5g str\u00f6m eller l\u00e5ngvarig statisk elektricitet.<\/p>\n\n\n\n


2SOCl2 + 4Li \u2192 4LiCl + SO2 + S<\/p>\n\n\n\n

Litiumsubbatterier \u00e4r icke-uppladdningsbara litiummetallbatterier, vars elektrolyt och katodmaterial \u00e4r tionylklorid. N\u00e4r metalllitium och tionylklorid reagerar under tiden bildas en litiumkloridoxidprodukt. Produkten f\u00e4ster p\u00e5 metallisk litiumoxid p\u00e5 ytan. Vi kallar detta oxidfilm (\u00e4ven kallad passiveringsfilm). Oxidfilmskiktet kan f\u00f6rhindra fortsatt snabb reaktion. Med andra ord har detta oxidfilmskikt en skyddande roll p\u00e5 katoden av metalllitium, vilket \u00e4r anledningen till att batteriet har l\u00e5ngtidslagringsegenskaper.<\/p>\n\n\n\n

\"\"<\/figure>\n\n\n\n

Efter bildandet av litiumkloridskyddsfilmen \u00e4r den interna stoppreaktionen endast relativ, inte absolut. Oavsett om den \u00e4r l\u00e4mplig f\u00f6r batterier med h\u00f6g urladdningsstr\u00f6m eller f\u00f6r batterier med l\u00e5g urladdningsstr\u00f6m, s\u00e5 l\u00e4nge batteriet har varit statiskt, kommer den interna, mycket l\u00e5ngsamma kemiska reaktionen att g\u00f6ra att passiveringsfilmen gradvis tjocknar. Passiveringsfilmens utseende g\u00f6r att litiumsubbatteriets interna resistans f\u00f6r\u00e4ndras \u00f6ver tid.<\/p>\n\n\n\n

Det \u00e4r genereringen av passiveringsfilm som g\u00f6r att den \u00e5rliga sj\u00e4lvurladdningshastigheten f\u00f6r litiumsubbatterier \u00e4r mycket liten vid rumstemperatur (energityp mindre \u00e4n 1%, effekttyp mindre \u00e4n 2%). Tillsammans med energit\u00e4theten hos litiumsubbatterier p\u00e5 upp till 700 Wh\/kg, litiumtionylkloridbatteri<\/a> har blivit den absoluta stj\u00e4rnprodukten inom omr\u00e5det f\u00f6r str\u00f6msn\u00e5l och l\u00e5ng livsl\u00e4ngd inom sakernas internet.
F\u00f6r n\u00e4rvarande kan inte laggfenomenet hos litiumsubbatterier helt l\u00f6sas med intern formel, men det kan elimineras med vissa metoder i praktisk till\u00e4mpning. ER14505M kan till exempel aktiveras genom att urladdas med ett 15-\u03c9-motst\u00e5nd i 10\u201320 minuter f\u00f6re anv\u00e4ndning om det f\u00f6rvaras i ett halv\u00e5r.<\/p>\n\n\n\n

Andra typer av litiumbatterier f\u00f6r l\u00e5ngtidslagring, eliminerar f\u00f6rdr\u00f6jning motsvarande s\u00e4kerhetsmotst\u00e5ndsstorlek och urladdningstid, v\u00e4nligen kontakta Langsheng f\u00f6r mer information.<\/p>","protected":false},"excerpt":{"rendered":"

The phenomenon of voltage hysteresis occurs when lithium subbattery is discharged with high current after long-term small current or long-term static storage. 2SOCl2 +4Li \u2192 4LiCl+SO2+ S Lithium subbattery is a non-rechargeable lithium metal battery, its electrolyte and cathode material are thionyl chloride. When metal lithium and thionyl chloride reaction time, will generate lithium chloride […]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"site-sidebar-layout":"default","site-content-layout":"default","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"default","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"footnotes":""},"categories":[1],"tags":[],"class_list":["post-3719","post","type-post","status-publish","format-standard","hentry","category-uncategorized"],"acf":[],"yoast_head":"\nVoltage hysteresis phenomenon of lithium thionyl chloride battery and its elimination method - Ahotech.com<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/www.ahotech.com\/sv\/2021\/11\/spanningshysteresfenomenet-hos-litiumtionylkloridbatterier-och-dess-elimineringsmetod\/\" \/>\n<meta property=\"og:locale\" content=\"sv_SE\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Voltage hysteresis phenomenon of lithium thionyl chloride battery and its elimination method - Ahotech.com\" \/>\n<meta property=\"og:description\" content=\"The phenomenon of voltage hysteresis occurs when lithium subbattery is discharged with high current after long-term small current or long-term static storage. 2SOCl2 +4Li \u2192 4LiCl+SO2+ S Lithium subbattery is a non-rechargeable lithium metal battery, its electrolyte and cathode material are thionyl chloride. 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