{"id":3719,"date":"2021-11-23T06:34:29","date_gmt":"2021-11-23T06:34:29","guid":{"rendered":"https:\/\/www.ahotech.com\/?p=3719"},"modified":"2021-11-24T12:15:41","modified_gmt":"2021-11-24T12:15:41","slug":"phenomene-dhysteresis-de-tension-des-batteries-au-lithium-chlorure-de-thionyle-et-methode-delimination","status":"publish","type":"post","link":"https:\/\/www.ahotech.com\/fr\/2021\/11\/voltage-hysteresis-phenomenon-of-lithium-thionyl-chloride-battery-and-its-elimination-method\/","title":{"rendered":"Ph\u00e9nom\u00e8ne d&#039;hyst\u00e9r\u00e9sis de tension des batteries au lithium-chlorure de thionyle et m\u00e9thode d&#039;\u00e9limination"},"content":{"rendered":"<p>Le ph\u00e9nom\u00e8ne d&#039;hyst\u00e9r\u00e9sis de tension se produit lorsque la sous-batterie au lithium est d\u00e9charg\u00e9e avec un courant \u00e9lev\u00e9 apr\u00e8s un faible courant \u00e0 long terme ou un stockage statique \u00e0 long terme.<\/p>\n\n\n\n<p><br>2SOCl2 +4Li \u2192 4LiCl+SO2+ S<\/p>\n\n\n\n<p>La batterie lithium-m\u00e9tal non rechargeable est compos\u00e9e d&#039;un \u00e9lectrolyte et d&#039;une cathode en chlorure de thionyle. La r\u00e9action entre le lithium et le chlorure de thionyle produit de l&#039;oxyde de chlorure de lithium. Ce produit se fixe \u00e0 la surface de l&#039;oxyde de lithium m\u00e9tallique\u00a0: on parle alors de film d&#039;oxyde (\u00e9galement appel\u00e9 film de passivation). Ce film d&#039;oxyde emp\u00eache la r\u00e9action rapide et continue. En d&#039;autres termes, ce film d&#039;oxyde sur la cathode joue un r\u00f4le protecteur, ce qui conf\u00e8re \u00e0 la batterie une longue dur\u00e9e de vie.<\/p>\n\n\n\n<figure class=\"wp-block-image size-large\"><img fetchpriority=\"high\" decoding=\"async\" width=\"1024\" height=\"461\" src=\"https:\/\/www.ahotech.com\/wp-content\/uploads\/2021\/11\/3.6-vc-cell-lithium-battery-1024x461.png\" alt=\"\" class=\"wp-image-3722\" srcset=\"https:\/\/www.ahotech.com\/wp-content\/uploads\/2021\/11\/3.6-vc-cell-lithium-battery-1024x461.png 1024w, https:\/\/www.ahotech.com\/wp-content\/uploads\/2021\/11\/3.6-vc-cell-lithium-battery-300x135.png 300w, https:\/\/www.ahotech.com\/wp-content\/uploads\/2021\/11\/3.6-vc-cell-lithium-battery-768x346.png 768w, https:\/\/www.ahotech.com\/wp-content\/uploads\/2021\/11\/3.6-vc-cell-lithium-battery-1536x691.png 1536w, https:\/\/www.ahotech.com\/wp-content\/uploads\/2021\/11\/3.6-vc-cell-lithium-battery-2048x922.png 2048w, https:\/\/www.ahotech.com\/wp-content\/uploads\/2021\/11\/3.6-vc-cell-lithium-battery-600x270.png 600w\" sizes=\"(max-width: 1024px) 100vw, 1024px\" \/><\/figure>\n\n\n\n<p>Apr\u00e8s la formation du film protecteur de chlorure de lithium, la r\u00e9action d&#039;arr\u00eat interne est relative et non absolue. Qu&#039;il soit adapt\u00e9 aux batteries \u00e0 courant de d\u00e9charge \u00e9lev\u00e9 ou faible, tant que la batterie est statique, la r\u00e9action chimique interne tr\u00e8s lente \u00e9paissit progressivement le film de passivation. L&#039;apparition de ce film de passivation modifie la r\u00e9sistance interne de la batterie au lithium au fil du temps.<\/p>\n\n\n\n<p>C&#039;est la formation d&#039;un film de passivation qui rend le taux d&#039;autod\u00e9charge annuel des batteries lithium-ion tr\u00e8s faible \u00e0 temp\u00e9rature ambiante (type d&#039;\u00e9nergie inf\u00e9rieur \u00e0 1%, type de puissance inf\u00e9rieur \u00e0 2%). Associ\u00e9e \u00e0 une densit\u00e9 \u00e9nerg\u00e9tique pouvant atteindre 700 Wh\/kg, <a href=\"https:\/\/www.ahotech.com\/fr\/categorie-produit\/batterie-lithium-chlorure-de-thionyle-li-socl2\/\">batterie au lithium-chlorure de thionyle<\/a> est devenu le produit phare absolu dans le domaine des applications \u00e0 faible consommation et longue dur\u00e9e de vie de l&#039;Internet des objets.<br>\u00c0 l&#039;heure actuelle, le ph\u00e9nom\u00e8ne de retard des sous-batteries au lithium ne peut \u00eatre totalement r\u00e9solu par une formule interne, mais il peut \u00eatre \u00e9limin\u00e9 par certaines m\u00e9thodes en pratique. Par exemple, l&#039;ER14505M peut \u00eatre activ\u00e9e par d\u00e9charge avec une r\u00e9sistance de 15 \u03c9 pendant 10 \u00e0 20 minutes avant utilisation si elle est stock\u00e9e six mois.<\/p>\n\n\n\n<p>D&#039;autres types de batteries au lithium pour un stockage longue dur\u00e9e, \u00e9liminent le d\u00e9calage correspondant \u00e0 la taille de r\u00e9sistance de s\u00e9curit\u00e9 et au temps de d\u00e9charge, veuillez consulter Langsheng pour plus de d\u00e9tails.<\/p>","protected":false},"excerpt":{"rendered":"<p>The phenomenon of voltage hysteresis occurs when lithium subbattery is discharged with high current after long-term small current or long-term static storage. 2SOCl2 +4Li \u2192 4LiCl+SO2+ S Lithium subbattery is a non-rechargeable lithium metal battery, its electrolyte and cathode material are thionyl chloride. When metal lithium and thionyl chloride reaction time, will generate lithium chloride [&hellip;]<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_acf_changed":false,"site-sidebar-layout":"default","site-content-layout":"default","ast-site-content-layout":"","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","theme-transparent-header-meta":"default","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"default","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"footnotes":""},"categories":[1],"tags":[],"class_list":["post-3719","post","type-post","status-publish","format-standard","hentry","category-uncategorized"],"acf":[],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.3 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>Voltage hysteresis phenomenon of lithium thionyl chloride battery and its elimination method - Ahotech.com<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/www.ahotech.com\/fr\/2021\/11\/phenomene-dhysteresis-de-tension-des-batteries-au-lithium-chlorure-de-thionyle-et-methode-delimination\/\" \/>\n<meta property=\"og:locale\" content=\"fr_FR\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Voltage hysteresis phenomenon of lithium thionyl chloride battery and its elimination method - Ahotech.com\" \/>\n<meta property=\"og:description\" content=\"The phenomenon of voltage hysteresis occurs when lithium subbattery is discharged with high current after long-term small current or long-term static storage. 2SOCl2 +4Li \u2192 4LiCl+SO2+ S Lithium subbattery is a non-rechargeable lithium metal battery, its electrolyte and cathode material are thionyl chloride. 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